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Today’s Lecture Notes
Summary:
A lot of what we did today rehashs the electrophilic aromatic substitution. We went over how nitro substituent would affect whether the incoming E+ would go to the ortho, meta, or para position. We also talked about how multiple subsituents would affect where the incoming E+ is going.
The next part is the nucleophilic substitution. The mechanism is a bit different and requires an electron withdrawing subsituent already on the aromatic ring. First, the (Nuc-) would attack a site with good leaving group (Cl-), then the double bond withdraws to the carbon with the EWG forming a carboanion. Then, the carbonanion comes down and kick the leaving group out, reforming the aromaticity.
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on Monday, January 31st, 2005 at 12:43 pm and is filed under CHM 2211.
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February 13th, 2005 at 8:46 pm
If the -OH is on the right its D not. This is an awesome study tool.